Coastal air is often described as fresh, clean, and salty. In many places, winds coming off the ocean can dilute urban pollution and replace stagnant air with cleaner marine air. But coastlines also create some of the most complicated air-quality environments on Earth.
Breaking waves release salt and biological material into the atmosphere. Sea breezes can move pollution inland—or return pollution that previously drifted offshore. Ports and ships add combustion emissions, while polluted coastal water can sometimes transfer material back into the air through sea spray.
Air quality near the coast is therefore shaped by a constant exchange between land, ocean, weather, and human activity.
Breaking Waves Create Natural Particulate Matter
Anyone who has stood near rough surf has experienced sea spray.
When waves break, bubbles form beneath the water and rise toward the surface. As those bubbles burst, they launch microscopic droplets into the atmosphere. Some droplets quickly lose their water through evaporation, leaving small particles containing sea salt and other materials that were present in the seawater.
These particles are known as sea-spray aerosol.
Sea salt is one of the world’s major natural sources of atmospheric particulate matter. Production generally increases with stronger winds and breaking waves, particularly in the surf zone.
Unlike soot or combustion particles, sea-spray particles are naturally produced. However, they still contribute to the total amount and chemistry of particulate matter in coastal air.
Salt particles also absorb water easily. During humid conditions, they can grow larger as they take up moisture, increasing how strongly they scatter light and contributing to the hazy appearance sometimes seen along coastlines.
Ocean Particles Are More Than Salt
Seawater is biologically active.
Tiny organisms, organic compounds, proteins, lipids, and other biological materials accumulate near the ocean surface. When bubbles burst, some of this material can become incorporated into sea-spray particles.
Marine microorganisms also influence the atmosphere through gases.
Phytoplankton produce a sulfur-containing compound called dimethyl sulfide, or DMS. After DMS escapes from the ocean, chemical reactions in the atmosphere can transform it into sulfur-containing compounds and eventually sulfate particles.
These tiny particles can help water vapor condense into cloud droplets.
The ocean therefore does more than receive material from the atmosphere. Marine biology actively contributes chemicals that influence particles, clouds, and atmospheric chemistry above the sea.
Sea Breezes Can Clean the Air
Coastlines regularly develop local wind patterns because land and water heat at different rates.
During a sunny day, land usually warms more quickly than the ocean. Warm air over the land rises, and cooler marine air moves inland to replace it. This creates a sea breeze.
When the incoming marine air is relatively clean, the sea breeze can improve conditions along the coast by pushing accumulated urban pollution farther inland and increasing atmospheric mixing.
This is one reason some coastal locations experience sudden improvements in temperature and air quality when an afternoon sea breeze arrives.
But the same circulation can create the opposite effect.
Sea Breezes Can Bring Pollution Back
Air pollution does not stop when it reaches the shoreline.
Emissions from cities, highways, power plants, and industrial areas can drift offshore during certain wind conditions. Cooler air above the water may remain relatively stable, preventing pollutants from mixing upward as efficiently as they would over heated land.
Pollution can therefore remain concentrated in a shallow layer over the water.
When the sea breeze develops later in the day, that polluted air may be carried back toward shore.
This process is particularly important for ground-level ozone. Nitrogen oxides and volatile organic compounds released by urban areas can react in sunlight while traveling over coastal waters. The resulting ozone may then return inland with the afternoon breeze.
Coastal areas around Long Island Sound, Lake Michigan, Chesapeake Bay, and other large bodies of water have experienced this type of pollution transport.
A beach may therefore be located far from the urban source of the pollution affecting it.
Salt Can Change Urban Pollution Chemistry
Sea-spray particles do not simply mix physically with urban air. They can participate in chemical reactions.
Sodium chloride particles provide surfaces and chloride ions that interact with nitrogen compounds, ozone, and other pollutants.
These reactions can change the chemical composition of both particles and gases and influence how pollutants are transported or deposited.
Marine iodine compounds can also participate in atmospheric chemistry and contribute to ozone destruction under some conditions.
These interactions make coastal air-quality modeling more complicated than simply adding “ocean air” and “city air” together.
The chemistry changes after they meet.
Ports Add Human-Made Pollution
Many of the world’s largest cities developed along coastlines because ports provide access to international trade.
That creates another important coastal air-quality influence.
Ships, tugboats, ferries, locomotives, cargo-handling equipment, trucks, generators, refineries, and warehouses may all operate within the same coastal region.
Diesel engines can release nitrogen oxides, particulate matter, carbon monoxide, sulfur oxides, and air toxics. Communities located near major ports may therefore experience considerably different air from an undeveloped stretch of coastline.
Modern ports are reducing these emissions through cleaner engines, lower-sulfur fuels, electric cargo equipment, shore power for docked vessels, and programs that reduce unnecessary engine operation.
The coast itself is not creating this pollution, but coastal geography influences where those emissions travel.
Polluted Water Can Potentially Become Polluted Air
One of the more surprising coastal research areas involves contamination moving from water back into the atmosphere.
If coastal water contains sewage, microorganisms, algal toxins, or other contaminants, breaking waves can potentially incorporate some of that material into sea-spray aerosols.
Researchers have documented the aerosolization of sewage-associated bacteria in coastal areas affected by polluted water and are continuing to investigate how effectively viruses, toxins, and other contaminants may move from water into air.
This does not mean ordinary sea spray should be considered dangerous.
The concern is greatest where coastal waters themselves are heavily contaminated. It demonstrates another reason water quality and air quality cannot always be treated as separate environmental issues.
Every Coast Creates a Different Atmosphere
Coastal air quality depends heavily on local conditions.
A remote rocky coastline exposed to strong ocean winds may experience extremely clean air dominated by natural marine aerosols. A densely populated harbor may contain sea salt mixed with traffic exhaust, ship emissions, industrial pollution, and secondary ozone.
Temperature, humidity, wind direction, waves, biological activity, nearby mountains, and the shape of bays and inlets all affect the result.
Even time of day can matter. A location experiencing clean offshore winds in the morning may receive recirculated pollution during an afternoon sea breeze.
The familiar smell and feel of coastal air therefore represent far more than salt water.
Coastlines are boundaries where two enormous environmental systems meet. The ocean sends particles and gases upward, the atmosphere deposits material back into the water, and coastal winds repeatedly move both natural and human-made pollution between land and sea.
The air along the shore is not simply cleaner or dirtier than inland air. It is chemically different—and constantly changing.
References
- https://www.epa.gov/cmaq/air-surface-exchange-process-overview
- https://www.epa.gov/sciencematters/modeling-research-shows-how-salty-ocean-air-impacts-ozone-pollution
- https://www.epa.gov/sciencematters/epa-scientists-collaborate-states-protect-long-island-sound-air-quality
- https://www.epa.gov/sciencematters/epa-projects-aim-improve-ozone-models-over-long-island-sound
- https://www.epa.gov/sciencematters/air-land-and-sea-tackling-ozone-issue-lake-michigans-shores
- https://www.epa.gov/ports-initiative/ports-primer-72-air-emissions
- https://www.epa.gov/ports-initiative/ocean-going-vessel-ogv-best-practices-improve-air-quality
- https://www.epa.gov/pm-pollution/health-and-environmental-effects-particulate-matter-pm
- https://www.pmel.noaa.gov/news-and-media/highlights/seasonal-variations-western-north-atlantic-marine-aerosol-properties
- https://www.aoml.noaa.gov/general/nchem.html
- https://csl.noaa.gov/news/2023/381_0629.html
- https://coastalscience.noaa.gov/project/aerosolized-coastal-water-pollution-impacts-study/
- https://science.nasa.gov/earth/earth-observatory/aerosols/

